Double α,α CH bond insertion into sp<sup>3</sup> CH<sub>2</sub> moiety: synthesis of a Fe carbene bis-hydride dinitrogen complex
نویسندگان
چکیده
Reduction of [(κ2-P, P′-PCH2PCy)FeCl2] 2 by two electrons under N2 resulted in the formation isomeric low spin diamagnetic complexes 3trans and 3cis [Fe(κ3-P,C,P′-PCPCy)(H)2(N2)] via successive CH bond insertions.
منابع مشابه
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2021
ISSN: ['1477-9234', '1477-9226']
DOI: https://doi.org/10.1039/d1dt00610j